Prologue: Bucky (2014)

The Red Room was known for training deadly assassins such as Natalia Romanova, the Black Widow. What they didn't intend to train, was Valeriya Villanova, an asset gone Rouge. But before she escaped the madness and became the monster she was always doomed to become, she met the Asset, a nameless man who she had more in common with than she thought. As Valeriya goes through her training to become the Black Widow she always thought she'd be, she ends up paving her own pathway to her destruction. Not even the Winter Soldier can save her...